There are two general classifications
of stone. The two classifications are siliceous and
calcareous.
Siliceous stones are composed of silica (SiO2) particles
and are very durable. Examples are granite, slate and
sandstone.
Calcareous stones are composed mostly of calcium carbonate
and are softer than the siliceous materials. Examples
are marble, travertine and limestone.
JerUSAlem Stone is a dolomite which falls in the calcareous
stone catagory. Dolomite stone (or Dolostone) are those
which contain more than 50% carbonate minerals of which
over half are dolomite minerals (calcium-magnesium carbonate).
Dolomite is considered carbonate rock.
What is Dolomitization
Although modem seawater
is supersaturated with respect to dolomite, dolomite
is not precipitating directly at an observable rate.
Dolomite is found in modem sabkas, peritidal environments,
and in some deep-sea sediments (Carballo et al. 1987,
Lumsden 1988, Tucker and Wright 1990). Dolomite formation
is controversial and many models have been proposed.
Popular models for dolomitization include burial dolomitization,
meteoric-seawater mixing, dolmitization by normal seawater,
and evaporation of brines. Most models include seawater
because it is the only known major reservoir to contain
the amount of Mg required for dolomitization (Purser
et al. 1994). Although some direct precipitation of
dolomite is thought to occur, the majority of dolomites,
in particular the massive dolomites of the Paleozoic
are believed to be the result of replacement of calcium
carbonate by dolomite (Sibley et al. 1994). The latter
involves two steps, the dissolution of calcite and the
precipitation of dolomite as indicated by the following
reactions:
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In modem sabkas, the periodic influx of seawater acts
as a source of M 2+ f or dolomitization. The precipitation
of evaporate minerals increases the Mg2/Ca2 ratio, a
factor known to promote dolomitization (Baker and Kastner
1981). Mixing of meteoric water and seawater has been
suggested for dolomitization by Badiozarnani (1973).
He indicates the mixing of proper proportions of the
two fluids can generate a nixed fluid which is undersaturated
with respect to calcite and supersaturated with respect
to dolomite. Although evidence of this model has been
found in Jamaica (Land 1977), it is generally not accepted
as an explanation for the massive dolomites (Sibley
et al. 1994). Evidence for the occurrence of dolomitization
by normal seawater was found at the Enewetak atoll (Sailer
1984). Whether the minor amounts of dolomite found in
deep sea sediments is the result of dolomitization by
normal seawater has not been determined.
The problem of the origin of natural dolomites is further
complicated by the fact precipitation of dolomite at
ambient conditions in the laboratory has not been successful.
Experimental studies involve the precipitation of dolomite
at temperatures greater than 100 O celsius and abnormally
high saturation states which do not represent modem
marine environments. However, catalysts and inhibitors
for the dolomitization reaction in the laboratory are
consistent with petrographic observations of natural
dolomites (Katz and Matthews 1977, Gaines 1980, Choquette
and Steinen 1980, Mackenzie 1981, Baker and Kastner
1981, Sibley 1982, Bullen and Sibley 1984, Gregg and
Sibley 1984, Saller 1984, Middleburg 1990, Fouke and
Reeder 1992, Sibley et al. 1994). Catalysts for dolomitization
include an increased Mg2/Ca2 ratio in the parent solution,
increased temperature, aragonite substrate (instead
of calcite), and increasing surface area of the substrate
(Katz and Matthews 1977, Baker and Kastner 1981, Sibley
and Bartlet 1987, Sibley 1990). Sibley et at. (I 987)
proposed the division of the dolomitization reaction
into an initial slow step, the induction period, followed
by the rapid replacement of the substrate by dolomite.
Further work by Nordeng and Sibley (1994) indicate the
reaction proceeds through a series of metastable products
progressively increasing in Mg. Sibley et al. (1994)
proposed the length of the induction period as an explanation
for the lack of marine dolomitization.
Limestone
Limestone rocks are those which contain more than 50%
calcite (calcium carbonate) mineral. Extensive karst
forms in limestone areas as the minerals react chemically
with dissolved carbon dioxide and organic acids. Although
limestone is slightly soluble in water, the reaction
with carbonic acid appears to be the primary solution
reaction. - Although calcite is usually the most abundant
mineral, other common minerals include aragonite, dolomite
and magnesite (magnesium carbonate). Impurities, which
tend to inhibit or slow down karstification, include
chert, flint, authigenic (formed in place) quartz and
feldspar, and clay minerals. Limestone is considered
a carbonate rock.
Dolomite
Dolomite rocks (or Dolostone) are those which contain
more than 50% carbonate minerals of which over half
are dolomite minerals (calcium-magnesium carbonate).
Because many dolomites appear to form by replacement
of limestone the rocks are usually crystalline. Although
dolomite may be slightly soluble in water, karst will
form in dolomite areas as the minerals react chemically
with dissolved carbon dioxide and organic acids. Although
calcite and dolomite are usually the most abundant minerals,
other common minerals include aragonite and magnesite
(magnesium carbonate). Impurities, which tend to inhibit
or slow down karstification, include chert, flint, authigenic
(formed in place) quartz and feldspar, and clay minerals.
Dolomite is considered carbonate rock.
Marble
Marble consists of metamorphosed limestone or dolomite
or both. Although marble may be slightly soluble in
water, karst will form in marble areas as the minerals
react chemically with dissolved carbon dioxide and organic
acids. Marble may be associated with contact or regional
metamorphism where phyllites, slates, schists, and metaquartzites
may be found. Marble is considered a carbonate rock.
How does Jerusalem
Stone compare with Marble?
Marble consists of metamorphosed limestone or dolomite
or both. Marble is considered a carbonate rock.
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